Cappuccino, C.; Tanwar, M.; Jia, X.; Hazari, N.; Donley, C. L.; Fakhraai, Z.; Manbeck, G. F.; Grills, D. C.; Polyansky, D. E. Unusual Electrochemical Activity of Thin SiO2 Layers Leads to Instability of Molecular Attachment in Hybrid Photoelectrodes. ACS Appl. Energy Mater., 2025, In press. https://doi.org/10.1021/acsaem.5c03010

Barba-Nieto, I.; Moncada, J.; Müller, A. V.; Rui, N.; Titus, C. J.; Jaye, C.; Meyer, G. J.; Concepcion, J. J.; Rodriguez, J. A. Following CO and H insertion into Ru-C bonds with X-ray photoelectron and absorption spectroscopies, Inorg. Chem., 2025, In press. https://doi.org/10.1021/acs.inorgchem.5c03822

Ortega Ortiz, E. V.; Yang, J.; Wang, H.; Stach, E. Quantitative Imaging of Cobalt Phthalocyanine Distribution on Carbon Nanotubes: A Deep Learning Approach to Catalyst Characterization, J. Phys. Chem. Lett., 2025, 129 (47), 20889-20896. https://doi.org/10.1021/acs.jpcc.5c04916

Bein, G. P.; Fernandez, S.; Tereniak, S. J.; Sampaio, R. N.; Miller, A. J. M.; Dempsey, J. L. Photosynthesis of CO from CO₂ with an Iron Polypyridyl Catalyst at a Passivated Silicon Photoelectrode, Chem. Sci., 2025, Advance Article. https://doi.org/10.1039/D5SC05984D

Teitsworth, T. S.; Rotundo, L.; Fang, H.; Tanwar, M.; Robinson, T.; Siegel, D. J.; Powers, R. E.; Orr, A. D.; Harvey, A. K.; Sampaio, R. N.; Donley, C. L.; Atkin, J. M.; Dempsey, J. L.; Fakhraai, Z.; Manbeck, G. F.; Tereniak, S. J.; Lockett, M. R. Potential-controlled Deposition of Multilayer CO2 Reduction Catalyst Films onto Silicon Photoelectrodes Demonstrates Thickness-dependent Catalytic Rate, ACS Appl. Mater. Interfaces, 2025, 17 (45), 62044–62052. https://doi.org/10.1021/acsami.5c15759

Fernandez, P.; Garcia-Batlle, M.; Shang, B.; Wang, H.; Parsons, G. N.; Cahoon, J. F.; Lopez, R. The importance of CO supersaturation and surface area—not geometry—for tandem single-catalyst CO₂ reduction to CH₃OH, 2025, ChemRxiv. https://doi.org/10.26434/chemrxiv-2025-743st

Barakat, M.; Fosu, E. A.; Jakubikova, E. Cobalt(II) Phthalocyanine Substituents Tune the Electrocatalytic CO2 Conversion to Methanol, Inorg. Chem.,2025, 64 (42), 20896-20906. https://doi.org/10.1021/acs.inorgchem.5c02279

Smith, A.; Tereniak, S.; Cox, H.; Massey, M.; Schauer, C.; Miller, A. CO Reduction to Ethylene and Cyclopropane via a Trappable Ruthenium Methylidene, J. Am. Chem. Soc., 2025, 147 (42), 38365-38375. https://doi.org/10.1021/jacs.5c11327

Nedzbala, H. S.; Powers, R. E.; Knapp, A. S.; Yang, H.; Gentile, R.; Vecchi, P.; Dickenson, J. C.; Sirlin, J. T.; Donley, C. L.; Chua, K.; Griffin, P.; Müller, A. V.; Sampaio, R. N.; Jackson, M. N.; Parsons, G. N.; Concepcion, J. J.; Cahoon, J. F.; Meyer, G. J.; Miller, A. J. M.; Dempsey, J. L.; Mayer, J. M. Photoelectrochemical Hydride Generation with Oxide-Coated Silicon, J. Am. Chem Soc., 2025, 147 (41), 37123-37132. https://doi.org/10.1021/jacs.5c08666

Chung, H. W.; Wang, H.-C.; Desai, S. P.; Müller, A. V.; Sena, S.; Glusac, K. D.; Concepcion, J. J.; Surendranath, Y. Reversible Interfacial Hydride Transfer as a Complementary Tool To Measure Molecular Hydricity, J. Am. Chem. Soc., 2025, 147 (40), 36291-36300. https://doi.org/10.1021/jacs.5c09582

You, J. M.; Chow, M.; Paenurk, E.; Hammes-Schiffer, S. Reliable pKa Prediction through Efficient Incorporation of Anharmonicity within the Nuclear–Electronic Orbital Framework, J. Am. Chem. Soc., 2025, 147 (40), 36059-36065. https://doi.org/10.1021/jacs.5c11332

McGuigan, S.; Donley, C. L.; Ortega Ortiz, E.; O’Donnell, S.; Pauly, M.; Hockaday, W. C.; Stach, E. A.; Maggard, P. A. Molecular Modifications of Crystalline Poly(triazine imide) for Advancing Its Structure–Property Relationships in Light-Driven Catalysis, Chem. Mater., 2025, 37 (19), 7656-7670. https://doi.org/10.1021/acs.chemmater.5c01007

Tereniak, S. J.; Butler, B. J. A new synthetic method of [Ru(2,2′:6′,2″-terpyridine)(2,2′-bipyridine)Cl]⁺ complexes using cis-[Ru(2,2′:6′,2″-terpyridine)(NCCH₃)₂Cl]+ as an intermediate and comparison to a method using [Ru(benzene)(2,2′-bipyridine)Cl]⁺ intermediates, Inorg. Chim. Acta, 2025, 589, 122892, https://doi.org/10.1016/j.ica.2025.122892.

Liu, S.; Xu, J.; Kanai, Y. Constrained Nuclear-Electronic Orbital Method for Periodic Density Functional Theory: Application to H2 Chemisorption on Si(001) Surfaces, J. Chem. Phys., 2025, 163, 084110. https://doi.org/10.1063/5.0278375

Travis, B. D.; Ertem, M. Z.; Hearne, W. A.; Gonell, S.; Miller, A. J. M. Unexpected Hydricity of a Bis-Carbene Iridium Complex Provides Insight into Electronic Structure Impacts on Hydride Donor Ability, Inorg. Chem., 2025, 64 (34), 17255–17265. https://doi.org/10.1021/acs.inorgchem.5c02249

Müller, A. V.; Desai, S. P.; Cappuccino, C.; Donley, C. L.; Miller, A. J. M.; Mayer, J. M.; Grills, D. C.; Polyansky, D. E.; Concepcion, J. J. Regeneration of Benzimidazole-Based Organohydrides Mediated by Ru Catalysts, ACS Catal., 2025, 15, 14996-15008. https://doi.org/10.1021/acscatal.5c01872

Kumar, S.; Fernández, S.; Saltsman, I.; Fridman, N.; Mahammed, A.; Miller, A. J. M.; Gross, Z. Substituents effects on the electrocatalytic CO₂ reduction by cobalt corroles in solution, Chem. Commun., 2025, 61, 12924-12927. https://doi.org/10.1039/D5CC02717A

Smith, A. M.; Fernández, S.; Tereniak, S. J.; Ahmad, S.; Kumar, A.; Chen, C.-H.; Hazari, N.; Ertem, M. Z.; Miller, A. J. M. Catalytic Hydrogenation of a Ruthenium Carbonyl to Formyl Enabled by Metal–Ligand Cooperation, ACS Catal., 2025, 15 (15), 13526–13533. https://doi.org/10.1021/acscatal.5c03137

Vecchi, P.; Dickenson, J. C.; Gentile, R. J.; Powers, R. E.; Dempsey, J. L.; Grills, D. C.; Cahoon, J. F.; Sampaio, R. N.; Meyer, G. J In-situ Characterization of Surface Recombination in p-Si/SiOx Based Photoelectrochemical Cells. ACS Electrochemistry, 2025, 1 (8), 1500-1514. https://doi.org/10.1021/acselectrochem.5c00098

Alameh, R.; Arteta, S.; Fernández, S.; Barakat, M.; Asempa, E.; Atallah, H.; Durand, N.; Gillis, C.; Assaf, E.; Jakubikova, E.; Miller, A.; Castellano, F. A Rhenium Bis-Tetramethylphenanthroline Catalyst for CO2 Reduction to Formate, Energy & Fuels, 2025, 39(26), 12667-12675. https://doi.org/10.1021/acs.energyfuels.5c01212