Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiO₂
Whittemore, T.; Schmalle, M.; Ryndin, E.; Spitler, M.; Brohmer, E. H. P.; Rau, S.; Zedler, L.; Danilov, E. O.; Castellano, F. N.; Kupfer, S.; Meyer, G.; Sorsche, D. Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiO2. J. Am. Chem. Soc. 2026. https://doi.org/10.1021/jacs.5c22325
A Monolithic Artificial Leaf for Solar Methanol Production from CO₂ and H₂O
Shang, B.; Yu, K.; Margavio, H. R. M.; Yang, H.; Gao, Y.; Yang, J.; Li, J.; Li, M.; Shi, J.; Liu, M.; Parsons, G. N.; Dempsey, J. L.; Meyer, G. J.; Mallouk, T. E.; Wang, H. A Monolithic Artificial Leaf for Solar Methanol Production from CO2 and H2O. J. Am. Chem. Soc.2026. https://doi.org/10.1021/jacs.6c04213
Advanced pathways for hydrogen production: a collective view from a technical experts meeting
Chou, K. J.; Acevedo, Y.; Agbo, P.; Bayon, A.; Beliaev, A. S.; Beyenal, H.; Croft, T.; Elgowainy, A.; Esposito, D. V.; Falter, C.; Ginley, D. S.; Haussener, S.; Hu, S.; Koepf, E.; Kumar, D.; Lidor, A.; Logan, B. E.; Loutzenhiser, P.; Mandalika, A. S.; Maness, P.; Meyer, G. J.; Nathan, G. J.; Rossi, R.; Stechel, E. B.; Sundstrom, E. R.; Warren, E.; Wendt, L. M.; Xiang, C.; McDaniel, A. H.; Houle, F. A. Advanced Pathways for Hydrogen Production: A Collective View from a Technical Experts Meeting. Energy Environ. Sci. 2026, 19 (8), 2507–2535. https://doi.org/10.1039/d5ee04503g
Finite-element-based simulations of electrodes for CO₂ cascade reduction reactions
García-Batlle, M.; Fernandez, P.; Parsons, G. N.; Cahoon, J. F.; Lopez, R. Finite-Element-Based Simulations of Electrodes for CO2 Cascade Reduction Reactions. Chemical Physics Reviews 2026, 7 (1), 011314. https://doi.org/10.1063/5.0269752
Quantitative Analysis of the Semiconductor–Electrolyte Interface Using Cyclic Voltammetry Measurements
Vecchi, P.; Goodwin, M. J.; Leimkuhl, D. P.; Dickenson, J. C.; Bein, G. P.; Jackson, M. N.; Cahoon, J. F.; Dempsey, J. L.; Meyer, G. J.; Sampaio, R. N. Quantitative Analysis of the Semiconductor–Electrolyte Interface Using Cyclic Voltammetry Measurements. J. Am. Chem. Soc. 2026, 148 (10), 10491–10505. https://doi.org/10.1021/jacs.5c18135
Reaction Diffusion Modelling of 3D Pillar Electrodes in Single-Catalyst CO₂ Reduction Cascade
Fernandez, P.; García-Batlle, M.; Shang, B.; Wang, H.; Parsons, G. N.; Cahoon, J. F.; Lopez, R. Reaction Diffusion Modelling of 3D Pillar Electrodes in Single-Catalyst CO2 Reduction Cascades. Electrochem 2026, 7 (1), 5. https://doi.org/10.3390/electrochem7010005
Concerted Proton–Electron Transfer Minimizes Substituent Effects on Adsorbed Phthalocyanine Electrocatalysis
Mannava, V.; Smith, L. E.; Gardner, J. G.; Hammes-Schiffer, S.; Surendranath, Y. Concerted proton-electron transfer minimizes substituent effects on adsorbed phthalocyanine electrocatalysis, J. Am. Chem. Soc., 2026, 148 (7), 6939-6950. https://doi.org/10.1021/jacs.5c16528
Exfoliation of Cu-Containing Poly(triazine imide): From Three-Dimensional to Two-Dimensional Particle Morphology
McGuigan, S.; Ortiz, E. O.; Jeon, S.; Donley, C. L.; Stach, E. A.; Maggard, P. A. Exfoliation of Cu-Containing Poly(Triazine Imide): From Three-Dimensional to Two-Dimensional Particle Morphology. Langmuir 2026, 42 (6), 4489–4496. https://doi.org/10.1021/acs.langmuir.5c05167
Gerischer Electrochemistry Today
Sambur, J. B.*;…; Meyer, G. J.; Cahoon, J. F.; Mayer, J. M.; Dempsey, J. L.; Sampaio, R. N.; Suo, S.; et al. Gerischer Electrochemistry Today, ACS Energy Let., 2025, 10 (12), 6578-6595. https://doi.org/10.1021/acsenergylett.5c02966
Unusual Electrochemical Activity of Thin SiO₂ Layers Leads to Instability of Molecular Attachment in Hybrid Photoelectrodes
Cappuccino, C.; Tanwar, M.; Jia, X.; Hazari, N.; Donley, C. L.; Fakhraai, Z.; Manbeck, G. F.; Grills, D. C.; Polyansky, D. E. Unusual Electrochemical Activity of Thin SiO2 Layers Leads to Instability of Molecular Attachment in Hybrid Photoelectrodes. ACS Appl. Energy Mater., 2025, In press. https://doi.org/10.1021/acsaem.5c03010
Following CO and H Insertion into Ru–C Bonds with X-ray Photoelectron and Absorption Spectroscopies
Barba-Nieto, I.; Moncada, J.; Müller, A. V.; Rui, N.; Titus, C. J.; Jaye, C.; Meyer, G. J.; Concepcion, J. J.; Rodriguez, J. A. Following CO and H insertion into Ru-C bonds with X-ray photoelectron and absorption spectroscopies, Inorg. Chem., 2025, In press. https://doi.org/10.1021/acs.inorgchem.5c03822
Quantitative Imaging of Cobalt Phthalocyanine Distribution on Carbon Nanotubes: A Deep Learning Approach to Catalyst Characterization
Ortega Ortiz, E. V.; Yang, J.; Wang, H.; Stach, E. Quantitative Imaging of Cobalt Phthalocyanine Distribution on Carbon Nanotubes: A Deep Learning Approach to Catalyst Characterization, J. Phys. Chem. Lett., 2025, 129 (47), 20889-20896. https://doi.org/10.1021/acs.jpcc.5c04916
Photosynthesis of CO from CO₂ with an iron polypyridyl catalyst at a passivated silicon photoelectrode
Bein, G. P.; Fernandez, S.; Tereniak, S. J.; Sampaio, R. N.; Miller, A. J. M.; Dempsey, J. L. Photosynthesis of CO from CO₂ with an Iron Polypyridyl Catalyst at a Passivated Silicon Photoelectrode, Chem. Sci., 2025, Advance Article. https://doi.org/10.1039/D5SC05984D
Potential-controlled Deposition of Multilayer CO₂ Reduction Catalyst Films onto Silicon Photoelectrodes Demonstrates Thickness-dependent Catalytic Rate
Teitsworth, T. S.; Rotundo, L.; Fang, H.; Tanwar, M.; Robinson, T.; Siegel, D. J.; Powers, R. E.; Orr, A. D.; Harvey, A. K.; Sampaio, R. N.; Donley, C. L.; Atkin, J. M.; Dempsey, J. L.; Fakhraai, Z.; Manbeck, G. F.; Tereniak, S. J.; Lockett, M. R. Potential-controlled Deposition of Multilayer CO2 Reduction Catalyst Films onto Silicon Photoelectrodes Demonstrates Thickness-dependent Catalytic Rate, ACS Appl. Mater. Interfaces, 2025, 17 (45), 62044–62052. https://doi.org/10.1021/acsami.5c15759
The importance of CO supersaturation and surface area—not geometry—for tandem single-catalyst CO₂ reduction to CH₃OH
Fernandez, P.; Garcia-Batlle, M.; Shang, B.; Wang, H.; Parsons, G. N.; Cahoon, J. F.; Lopez, R. The importance of CO supersaturation and surface area—not geometry—for tandem single-catalyst CO₂ reduction to CH₃OH, 2025, ChemRxiv. https://doi.org/10.26434/chemrxiv-2025-743st
Cobalt(II) Phthalocyanine Substituents Tune the Electrocatalytic CO₂ Conversion to Methanol
Barakat, M.; Fosu, E. A.; Jakubikova, E. Cobalt(II) Phthalocyanine Substituents Tune the Electrocatalytic CO2 Conversion to Methanol, Inorg. Chem.,2025, 64 (42), 20896-20906. https://doi.org/10.1021/acs.inorgchem.5c02279
CO Reduction to Ethylene and Cyclopropane via a Trappable Ruthenium Methylidene
Smith, A.; Tereniak, S.; Cox, H.; Massey, M.; Schauer, C.; Miller, A. CO Reduction to Ethylene and Cyclopropane via a Trappable Ruthenium Methylidene, J. Am. Chem. Soc., 2025, 147 (42), 38365-38375. https://doi.org/10.1021/jacs.5c11327
Photoelectrochemical Hydride Generation with Oxide-Coated Silicon
Nedzbala, H. S.; Powers, R. E.; Knapp, A. S.; Yang, H.; Gentile, R.; Vecchi, P.; Dickenson, J. C.; Sirlin, J. T.; Donley, C. L.; Chua, K.; Griffin, P.; Müller, A. V.; Sampaio, R. N.; Jackson, M. N.; Parsons, G. N.; Concepcion, J. J.; Cahoon, J. F.; Meyer, G. J.; Miller, A. J. M.; Dempsey, J. L.; Mayer, J. M. Photoelectrochemical Hydride Generation with Oxide-Coated Silicon, J. Am. Chem Soc., 2025, 147 (41), 37123-37132. https://doi.org/10.1021/jacs.5c08666
Reversible Interfacial Hydride Transfer as a Complementary Tool To Measure Molecular Hydricity
Chung, H. W.; Wang, H.-C.; Desai, S. P.; Müller, A. V.; Sena, S.; Glusac, K. D.; Concepcion, J. J.; Surendranath, Y. Reversible Interfacial Hydride Transfer as a Complementary Tool To Measure Molecular Hydricity, J. Am. Chem. Soc., 2025, 147 (40), 36291-36300. https://doi.org/10.1021/jacs.5c09582
Reliable pKₐ Prediction through Efficient Incorporation of Anharmonicity within the Nuclear–Electronic Orbital Framework
You, J. M.; Chow, M.; Paenurk, E.; Hammes-Schiffer, S. Reliable pKa Prediction through Efficient Incorporation of Anharmonicity within the Nuclear–Electronic Orbital Framework, J. Am. Chem. Soc., 2025, 147 (40), 36059-36065. https://doi.org/10.1021/jacs.5c11332