Garcia-Batlle, M.; Fernandez, P.; Sheehan, C.; He, S.; Mallouk, T.; Parsons, G.; Cahoon. J.; Lopez, R. Spatially Patterned Architectures to Modulate CO₂ Reduction Cascade Catalysis Kinetics. ACS Catalysis, 2025, In press. https://doi.org/10.1021/acscatal.5c01176

He, S.; Bottum, S. R.; Dickenson, J. C.; Margavio, H. R. M.; Keller, N. D.; Oyetade, O. A.; Gentile, R. J.; Teitsworth, T. S.; Shin, S. J.; Dempsey, J. L.; Miller, A. J. M.; Sampaio, R. N.; Tereniak, S. J.; Donley, C. L.; Lockett, M. R.; Parsons, G. N.; Meyer, G. J.; Cahoon, J. F. Electron Inversion and Tunneling at Silicon Thermal Oxide Interfaces for Solar-Driven Molecular Catalysis to Syngas, J. Am. Chem. Soc., 2025, In press. https://doi.org/10.1021/jacs.4c17251

Rooney, C. L.; Sun, Q.; Shang, B.; Wang, H. Electrocatalytic Reductive Amination of Aldehydes and Ketones with Aqueous Nitrite, J. Am. Chem. Soc., 2025, in press. https://doi.org/10.1021/jacs.4c16344

Hong, Y. H.; Jia, X.; Stewart-Jones, E.; Kumar, A.; Wedal, J. C.; Alvarez-Hernandez, J. L.; Donley, C. L.; Gang, A.; Gibson, N. J.; Hazari, N. Houck, M.; Jeon, S.; Kim, J.; Koh, H.; Mayer, J. M.; Mercado, B. Q.; Nedzbala, H. S.; Piekut, N.; Quist, C.; Stach, E.; Zhang, Y. Photoelectrocatalytic reduction of CO₂ to formate using immobilized molecular manganese catalysts on oxidized porous silicon, Chem, 2025, 102462. https://doi.org/10.1016/j.chempr.2025.102462

Sheehan, C. J.; Suo, S.; Jeon, S.; Zheng, Y.; Meng, J.; Zhao, F.; Yang, Z.; Xiao, L.; Venkatesan, S.; Metlay, A. M.; Donley, C. L.; Stach, E. A.; Lian, T.; Mallouk, T. E. Electron Transfer Energetics in Photoelectrochemical CO₂ Reduction at Viologen Redox Polymer-Modified p-Si Electrodes, J. Am. Chem. Soc., 2025, In press. https://doi.org/10.1021/jacs.4c17762

Yang, H.; Oldham, C. J.; Donley, C. L.; Sampaio, R. N.; Dickenson, J. C.; Vecchi, P.; Reddy, K. A. J.; Maggard, P. A.; Meyer, G. J.; Parsons, G. N. Mild-Annealed Molecular Layer Deposition (MLD) Tincone Thin Film as Photoelectrochemically Stable and Efficient Electron Transport Layer for Si Photocathodes, ACS Appl. Energy Mater., 2025, 8 (5), 2982–2992. https://doi.org/10.1021/acsaem.4c02997

Alameh, R. T.; Rosko, M. C.; Danilov, E. O.; Durand, N.; Castellano, F. N. Photophysical and Time-resolved Infrared Properties of Long-Lived Rhenium(I) 4,5-Diazafluorene Tricarbonyl Chromophores, ChemPhysChem, 2025, e202500008. https://doi.org/10.1002/cphc.202500008

Bredar, A. R. C.; Margavio, H. R. M.; Donley, C. L.; Spinner, N.; Amin, N.; Parsons, G. N.; Dempsey, J. L. Oxidation Temperature-Dependent Electrochemical Doping of WO3 Deposited via Atomic Layer Deposition, J. Phys. Chem. C., 2024, 128 (50), 21539-21550. https://doi.org/10.1021/acs.jpcc.4c06105

Jeon, S.; Nedzbala, H.; Huffman, B.; Pearce, A.; Donley, C.; Jia, X.; Bein, G.; Choi, J. H.; Durand, N.; Atallah, H.; Castellano, F.; Dempsey, J. L.; Mayer, J.; Hazari, N. Statistical Analysis of HAADF-STEM Images to Determine the Surface Coverage and Distribution of Immobilized Molecular Complexes. Matter, 2025, 8 (2), 101919. https://doi.org/10.1016/j.matt.2024.11.013

• Highlighted here in Penn Today Press Release!

Wang, H.; Shang, B.; Choi, C.; Jeon, S.; Gao, Y.; Wang, T.; Harmon, N. J.; Liu, M.; Stach, E. A.; Wang, H. Enhanced methanol production from photothermal CO2 reduction via multilevel interface design, Nano. Res., 2025, 18 (2), 94907160. https://doi.org/10.26599/NR.2025.94907160

Fernández, S.; Assaf, E.; Ahmad, S.; Travis, B.; Curley, J.; Hazari, N.; Ertem, M. Z.; Miller, A. J. M. Room Temperature Formate Ester Transfer Hydrogenation Enables an Electrochemical-Thermal Organometallic Cascade for Methanol Synthesis from CO2. Angew. Chem. Int. Ed. 2024, 64 (4), e202416061.. https://doi.org/10.1002/anie.202416061

Xu, J.; Zhou, R.; Li. T. E.; Hammes-Schiffer, S.; Kanai, Y. Lagrangian Formulation of Nuclear-Electronic Orbital Ehrenfest Dynamics with Real-time TDDFT for Extended Periodic Systems. J. Chem. Phys., 2024, 161, 194109. https://doi.org/10.1063/5.0230570

Concepcion, J. J.; Sampaio, R. N.; Meyer, G. J. “Catalytic Reduction of Carbon Monoxide to Liquid Fuels with Recyclable Hydride Donors” ACS Catal., 2024, (14), 16562-16569. https://doi.org/10.1021/acscatal.4c05083

Rotundo, L.; Ahmad, S.; Cappuccino, C.; Pearce, A. J.; Nedzbala, H.; Bottum, S. R.; Mayer, J. M.; Cahoon, J. F.; Grills, D. C.; Ertem, M. Z.; Manbeck, G. F. Fast Catalysis at Low Overpotential: Designing Efficient Dicationic Re(bpy²⁺)(CO)₃I Electrocatalysts for CO₂ Reduction, J. Am. Chem. Soc., 2024, 146 (36), 24742-24747. https://doi.org/10.1021/jacs.4c08084

Hart, M.; Idanwekhai, K.; Alves, V. M.; Miller, A. J. M.; Dempsey, J. L.; Cahoon, J. F.; Chen, C-H.; Winkler, D. A.; Muratov, E. N.; Tropsha, A. Trust Not Verify? The Critical Need for Data Curation Standards in Materials Informatics, Chem. Mater., 2024, 36 (19), 9046-9055. https://doi.org/10.1021/acs.chemmater.4c00981

Teitsworth, T. S.; Fang, H.; Harvey, A. K.; Orr, A. D.; Donley, C. L.; Fakhraai, Z.; Atkin, J. M.; Lockett, M. R. Diazonium-Functionalized Silicon Hybrid Photoelectrodes: Film Thickness and Composition Effects on Photoelectrochemical Behavior, Langmuir, 2024, 40 (34), 18133-18141. https://doi.org/10.1021/acs.langmuir.4c01787

Oyetade, O.; Wang, Y.; He, S.; Margavio, H.; Bottum, S.; Rooney, C.; Wang, H.; Donley, C.; Parsons, G.; Cohen-Karni, T.; Cahoon, J. Covalent Functionalization of Silicon with Plasma-grown ‘Fuzzy’ Graphene: Robust Aqueous Photoelectrodes for CO2 Reduction by Molecular Catalysts, ACS Appl. Mater. Interfaces, 2024, 16 (29), 37885–37895. https://doi.org/10.1021/acsami.4c04691

• Featured in UNC Chemistry News!

Barba-Nieto, I.; Müller, A. V.; Titus, C. J.; Wierzbicki, D.; Jaye, C.; Ertem, M. Z.; Meyer, G. J.; Concepcion, J. J.; Rodriguez, J. Formal Oxidation States and Coordination Environments in the Catalytic Reduction of CO to Methanol, ACS Energy Lett., 2024, 9, 3815-3817. https://pubs.acs.org/doi/10.1021/acsenergylett.4c01269

• Featured in DOE BES Science Highlight!

Hutchison, P.; Smith, L. E.; Rooney, C. L.; Wang, H.; Hammes-Schiffer, S. Proton-Coupled Electron Transfer Mechanisms for CO2 Reduction to Methanol Catalyzed by Surface-Immobilized Cobalt Phthalocyanine, J. Am. Chem. Soc., 2024, 146 (29) 20230-20240. https://doi.org/10.1021/jacs.4c05444

Smith, A. M.; Miller, A. J. M. Open Circuit Potential Method for Thermodynamic Hydricity Measurements of Metal Hydrides, Organometallics, 2024, 43 (24), 3163-3170. https://doi.org/10.1021/acs.organomet.4c00144