Synthesis of new chelating phosphines containing an aryl chloride group

The syntheses of bidentate and tripodal phosphine ligands containing aryl chlorides were achieved in 4 and 6 steps respectively, starting from diethylmalonate.

Genoux, A.; DiPrimio, D. J.; Tereniak, S. J.; Holland, P. Synthesis of new chelating phosphines containing an aryl chloride group. Synthesis 2023, 55 (17), 2737-2741. https://doi.org/10.1055/a-2090-8316

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Lewis Acids and Electron-Withdrawing Ligands Accelerate CO Coordination to Dinuclear Cu(I) Compounds

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Multi-Electron Transfer at H-Terminated p-Si Electrolyte Interfaces: Large Photovoltages under Inversion Conditions