Electrocatalytic methylation and amination reactions with CO₂ and NOₓʸ–

Implementing a chemical C–N coupling step to intercept reactive intermediatesin electrocatalytic CO2 or NOxy– reduction reactions is an emerging approach to sustainable electrosynthesis of organonitrogen compounds from cheap and abundant feedstocks.

Rooney, C.L.; Wang, H. Electrocatalytic methylation and amination reactions with CO₂ and NOₓʸ⁻, 2024, Nat. Synth. https://doi.org/10.1038/s44160-024-00565-x

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Absolute band-edge energies are over-emphasized in the design of photoelectrochemical materials

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Reductive Dynamic and Static Excited State Quenching of a Homoleptic Ruthenium Complex Bearing Aldehyde Groups